3-Chloro-N-phenyl-benzamide.
Ontology highlight
ABSTRACT:
SUBMITTER: Rodrigues VZ
PROVIDER: S-EPMC3238977 | biostudies-literature |
REPOSITORIES: biostudies-literature
Similar Datasets
Project description:In the title compound, C(13)H(9)ClFNO, the dihedral angle between the two aromatic rings is 13.6?(2)°. In the crystal, the mol-ecules are linked by inter-molecular N-H?O hydrogen bonds into chains extending along the c-axis direction.
| S-EPMC2977102 | biostudies-literature
Project description:The amide group in the structure of the title compound (N35DCP2CBA), C(13)H(8)Cl(3)NO, is trans-planar, similar to that observed in N-(3-chloro-phen-yl)benzamide, N-(3,5-dichloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide and other benzanilides. The C=O bond in N35DCP2CBA is anti to the ortho-chloro substituent in the benzoyl ring. The amide group makes dihedral angles of 63.1?(12) and 31.1?(17)°, respectively, with the benzoyl and aniline benzene rings, while the dihedral angle between the two benzene rings is 32.1?(2)°. The mol-ecules are linked into chains along the b axis by N-H?O hydrogen bonds.
| S-EPMC2961721 | biostudies-literature
Project description:In the title compound, C(13)H(10)ClNO, the dihedral angle between the two benzene rings is 59.6?(1)°. The crystal structure features N-H?O hydrogen bonds, which link the mol-ecules into C(4) chains running along the a axis.
| S-EPMC3238842 | biostudies-other
Project description:In the crystal structure of the title compound, C(13)H(9)Cl(2)NO, the N-H and C=O bonds are anti to each other in the two independent mol-ecules. In one mol-ecule, the N-H bond is syn to the meta-chloro group of the attached ring; it is anti in the other mol-ecule. This relationship is also observed between the C=O bond and the meta-chloro substituent of its attached ring. The amide -NHCO- group makes dihedral angles of 31.5?(4) and 34.7?(3)° with the aniline rings; it makes dihedral angles of 37.4?(3) and 37.2?(3)° with the benzoyl rings. The two rings are nearly coplanar, with dihedral angles of 9.1?(2) and 7.3?(3)° in the two independent mol-ecules. Adjacent mol-ecules are linked into infinite chains through N-H?O hydrogen bonds.
| S-EPMC2961234 | biostudies-literature
Project description:In the mol-ecular structure of the title compound, C(13)H(9)Cl(2)NO, the amide N-C=O plane makes dihedral angles of 31.53?(8) and 36.23?(8)°, respectively, with the 4-chloro- and 2-chloro-phenyl rings. The dihedral angle between the two benzene rings is 6.25?(8)°. The mol-ecules are stacked in columns along the b axis through inter-molecular N-H?O hydrogen bonds. The columns are further connected by weak C-H?O hydrogen bonds. The compound is not isomorphous with the fluoro analogue.
| S-EPMC2959385 | biostudies-literature
Project description:In the title compound, C(13)H(9)Cl(2)NO, the meta-Cl atom in the benzoyl ring is positioned anti to the C=O bond, while the ortho-Cl atom in the aniline ring is positioned syn to the N-H bond. The two aromatic rings are almost coplanar, making a dihedral angle of 4.73?(5)°. The crystal structure is stabilized by N-H?O hydrogen bonds, which link the mol-ecules into chains along the b axis.
| S-EPMC3254408 | biostudies-literature
Project description:In the structure of the the title compound, C(13)H(9)Cl(2)NO, the N-H and C=O groups are mutually trans. Furthermore, the conformation of the C=O group is syn to the ortho-chloro group in the benzoyl ring, while the N-H bond is anti to the meta-chloro group in the aniline ring. The amide group forms dihedral angles of 89.11?(19) and 22.58?(37)°, respectively, with the benzoyl and aniline rings, while the benzoyl and aniline rings form a dihedral angle of 69.74?(14)°. The mol-ecules are linked into infinite chains through inter-molecular N-H?O hydrogen bonds.
| S-EPMC2961659 | biostudies-literature
Project description:In the title benzamide derivative, C(11)H(14)ClNO, the chloro-benzene and butyl-amine groups are each planar, with mean deviations from the planes of 0.013 and 0.030?Å, respectively, and a dihedral angle of 2.54?(9)° between the two planes. In the crystal structure, N-H?O hydrogen bonds link mol-ecules in rows along a. Short inter-molecular Cl?Cl inter-actions [3.4225?(5)?Å] link these rows into sheets in the ac plane. Additional weak C-H?O and C-H?? inter-actions generate a three-dimensional network.
| S-EPMC2960128 | biostudies-literature
Project description:There are two mol-ecules in the asymmetric unit of the title compound, C(8)H(8)ClNO, which are linked in the crystal structure via N-H⋯O hydrogen bonds into chains along the b axis. C-H⋯O contacts also occur. The benzene ring makes dihedral angles of 5.9 (1) and 16.7 (1)°with the attached amide group in the two independent molecules.
| S-EPMC3343919 | biostudies-literature
Project description:In the crystal of the title compound, C(7)H(5)ClN(2)O(3), the molecules are linked by N-H⋯O and C-H⋯O hydrogen bonds. The π-π contact between the benzene rings, [centroid-centroid distance = 3.803 (3) Å] may further stabilize the structure.
| S-EPMC2967989 | biostudies-literature