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4-Chloro-N-methyl-benzamide.

ABSTRACT: There are two mol-ecules in the asymmetric unit of the title compound, C(8)H(8)ClNO, which are linked in the crystal structure via N-H⋯O hydrogen bonds into chains along the b axis. C-H⋯O contacts also occur. The benzene ring makes dihedral angles of 5.9 (1) and 16.7 (1)°with the attached amide group in the two independent molecules.

SUBMITTER: Yuan J

PROVIDER: S-EPMC3343919 | biostudies-literature |

REPOSITORIES: biostudies-literature

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N-(4-Chloro-phen-yl)-2-methyl-benzamide.

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Project description:In the title compound, C(14)H(12)ClNO, the two aromatic rings are almost coplanar, making a dihedral angle of 4.08?(18)°. In the crystal, N-H?O hydrogen bonds link the mol-ecules into infinite chains running along the a axis.

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N-(4-Chloro-phen-yl)-3-methyl-benzamide.

Project description:In the structure of the title compound, C(14)H(12)ClNO, the conformations of the N-H and C=O bonds are anti to each other. Furthermore, the conformation of the C=O bond is syn to the meta-methyl group in the benzoyl ring. The central -NH-C(=O)- amido group makes a dihedral angle of 32.4?(1)° with the benzoyl ring and 36.1?(1)° with the anilino ring. The dihedral angle between the two benzene rings is 68.4?(1)°. In the crystal, inter-molecular N-H?O hydrogen bonds link the mol-ecules into chains running along the a axis.

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Project description:In the mol-ecular structure of the title compound, C(14)H(12)ClNO, the meta-Cl atom in the benzoyl ring is positioned syn to the C=O bond, while the meta-methyl group in the aniline ring is positioned anti to the N-H bond. The two aromatic rings make a dihedral angle of 77.4 (1)°. In the crystal, the molecules are linked by N-H⋯O hydrogen bonds, forming C(4) chains propagating in [010].

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Project description:In the mol-ecular structure of the title compound, C(14)H(12)ClNO, the meta-Cl atom in the benzoyl ring is positioned anti to the C=O bond, while the ortho-methyl group in the aniline ring is positioned syn to the N-H bond. The two benzene rings are nearly coplanar [dihedral angle = 3.48 (5)°]. The crystal structure is stabilized by N-H⋯O hydrogen bonds, which link the mol-ecules into chains along the b axis.

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