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(E)-2-(4-Benz-yloxy-2-hy-droxy-benzyl-idene)-N-phenyl-hydrazinecarbothio-amide.

ABSTRACT: The title compound, C(21)H(19)N(3)O(2)S, exists in the thione form. The configuration about the C=N bond is E. The hydrazinecarbothio-amide unit adopts an almost planar arrangement, with maximum deviations of 0.016?(3) and -0.016?(2)?Å for the two thio-urea N atoms. An intra-molecular O-H?N hydrogen bond occurs. Weak inter-molecular N-H?S, C-H?O and C-H?? inter-actions are observed in the crystal structure.

SUBMITTER: Nisha K 

PROVIDER: S-EPMC3239056 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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(E)-2-(4-Benz-yloxy-2-hy-droxy-benzyl-idene)-N-phenyl-hydrazinecarbothio-amide.

Nisha K K   Sithambaresan M M   Kurup M R Prathapachandra MR  

Acta crystallographica. Section E, Structure reports online 20111125 Pt 12

The title compound, C(21)H(19)N(3)O(2)S, exists in the thione form. The configuration about the C=N bond is E. The hydrazinecarbothio-amide unit adopts an almost planar arrangement, with maximum deviations of 0.016 (3) and -0.016 (2) Å for the two thio-urea N atoms. An intra-molecular O-H⋯N hydrogen bond occurs. Weak inter-molecular N-H⋯S, C-H⋯O and C-H⋯π inter-actions are observed in the crystal structure. ...[more]

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