A monoclinic polymorph with Z = 4 of (E)-2,4-dihy-droxy-acetophenone 2,4-dinitro-phenyl-hydrazone N,N-dimethyl-formamide monosolvate.

ABSTRACT: The title compound, C(14)H(12)N(4)O(6)·C(3)H(7)NO, is a monoclinic polymorph of an already published structure [Baughman et al. (2004 ?). Acta Cryst. C60, 103-106]. In the previously reported structure, the compound crystallized in the triclinic space group P[Formula: see text] (Z = 2), whereas the structure reported here is monoclinic (P2(1)/n, Z = 4). In both forms, two intra-molecular hydrogen bonds result in the formation of a fairly planar hydrazone skeleton (r.m.s. deviations for all non-H atoms = 0.127?Å for the monoclinic from and 0.131?Å for the triclinic form) and each mol-ecule is hydrogen bonded to one solvent mol-ecule. The principal difference between the two forms lies in the different orientation of the two mol-ecules. In the monoclinic form, the two mol-ecules are almost coplanar [dihedral angle = 3.27?(2)°], whereas in the triclinic form the two mol-ecules are almost mutulally perpendicular (dihedral angle = 85.3°).

SUBMITTER: Han H 

PROVIDER: S-EPMC3239067 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature