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(E)-N'-(5-Chloro-2-hy-droxy-benzyl-idene)-2,4-dihy-droxybenzohydrazide methanol monosolvate.

ABSTRACT: In the title compound, C(14)H(11)ClN(2)O(4)·CH(3)OH, the mol-ecule adopts an E conformation about the C=N bond. The compound is in the enamine-keto form. The two terminal benzene rings make a dihedral angle of 10.53?(9)°. Intra-mol-ecular O-H?O and O-H?N hydrogen bonding stabilizes the mol-ecular structure. In the crystal, O-H?O hydrogen bonds link the mol-ecules, forming chains running along the b axis.

SUBMITTER: Li K

PROVIDER: S-EPMC3343942 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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(E)-N'-(5-Chloro-2-hy-droxy-benzyl-idene)-2,4-dihy-droxybenzohydrazide methanol monosolvate.

Li Kun K

Acta crystallographica. Section E, Structure reports online 20120307 Pt 4

In the title compound, C(14)H(11)ClN(2)O(4)·CH(3)OH, the mol-ecule adopts an E conformation about the C=N bond. The compound is in the enamine-keto form. The two terminal benzene rings make a dihedral angle of 10.53 (9)°. Intra-mol-ecular O-H⋯O and O-H⋯N hydrogen bonding stabilizes the mol-ecular structure. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules, forming chains running along the b axis. ...[more]

PMID: 22590023

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