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N,N',N''-Tricyclo-hexyl-guanidinium iodide.

ABSTRACT: In the title compound, C(19)H(36)N(3) (+)·I(-), the orientation of the cyclo-hexyl rings around the planar (sum of N-C-N angles = 360°) CN(3) (+) unit produces steric hindrance around the N-H groups. As a consequence of this particular orientation of the tricyclo-hexyl-guanidinium cation (hereafter denoted CHGH(+)), hydrogen bonding is restricted to classical N-H⋯I and non-clasical (cyclo-hex-yl)C-H⋯I hydrogen bonds. The propeller CHGH(+) cation and the oriented hydrogen-bonding interactions lead to a three-dimensional supra-molecular structure.

SUBMITTER: Said FF

PROVIDER: S-EPMC3239094 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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N,N',N''-Tricyclo-hexyl-guanidinium iodide.

Said Farouq F FF Ali Basem F BF Richeson Darrin D

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

In the title compound, C(19)H(36)N(3) (+)·I(-), the orientation of the cyclo-hexyl rings around the planar (sum of N-C-N angles = 360°) CN(3) (+) unit produces steric hindrance around the N-H groups. As a consequence of this particular orientation of the tricyclo-hexyl-guanidinium cation (hereafter denoted CHGH(+)), hydrogen bonding is restricted to classical N-H⋯I and non-clasical (cyclo-hex-yl)C-H⋯I hydrogen bonds. The propeller CHGH(+) cation and the oriented hydrogen-bonding interactions lea ...[more]

PMID: 22199942

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