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[(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

ABSTRACT: In the title compound, [Au(C(10)H(11)N(2)O(3)S)(C(18)H(33)P)], the gold(I) atom is linearly coordinated within a SP donor set. The distortion from linearity [S-Au-P = 177.54?(3)°] can be traced to an intra-molecular Au?O contact of 3.009?(3)?Å. In the crystal, layers of mol-ecules are stabilized by a combination of C-H?O and C-H?? inter-actions.

SUBMITTER: Ho SY

PROVIDER: S-EPMC2971249 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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[(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Ho Soo Yei SY Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091023 Pt 11

In the title compound, [Au(C(10)H(11)N(2)O(3)S)(C(18)H(33)P)], the gold(I) atom is linearly coordinated within a SP donor set. The distortion from linearity [S-Au-P = 177.54 (3)°] can be traced to an intra-molecular Au⋯O contact of 3.009 (3) Å. In the crystal, layers of mol-ecules are stabilized by a combination of C-H⋯O and C-H⋯π inter-actions. ...[more]

PMID: 21578153

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