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Hexaaqua-cobalt(II) bis-(2,2'-sulfanediyldiacetato-κO,S,O')cobaltate(II) tetra-hydrate.

ABSTRACT: The two Co(II) atoms in the title salt, [Co(H(2)O)(6)][Co(C(4)H(4)O(4)S)(2)]·4H(2)O, exist in an octa-hedral coordination environment. In the cation, the Co atom is surrounded by six water mol-ecules, and in the anion, it is bis-O,S,O'-chelated by the thio-acetate ligands. The cations, anions and uncoordinated water mol-ecules are linked by O-H⋯O hydrogen bonds into a three-dimensional network.

SUBMITTER: Wang H

PROVIDER: S-EPMC3246949 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Tetra-aqua-bis-(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetra-hydrate.

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| S-EPMC2961946 | biostudies-literature

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Project description:The Co(II) atom in the title compound, [Co(C(8)H(5)O(3))(2)(H(2)O)(4)]·4H(2)O, which exists in an all-trans octa-hedral coordination geometry, lies on a center of inversion. The coordinated and uncoordinated water mol-ecules engage in extensive hydrogen-bonding inter-actions, forming a three-dimensional hydrogen-bonded network.

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