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4-(Dodec-yloxy)benzonitrile.

ABSTRACT: In the title compound, C(19)H(29)NO, the C-C and C-N bond distances of the benzonitrile group are 1.445 (2) and 1.157 (2) Å, respectively. The aliphatic fragment adopts a bent zigzag arangement which differs from the planar zigzag arrangement normally observed in n-alkanes or long-chain alkyl-benzenes. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds occur. A C-H⋯N inter-action also occurs. In the crystal, mol-ecules are packed with the nitrile and aliphatic groups oriented in a head-to-tail fashion involving, forming a ripple-like motif along the a axis.

SUBMITTER: Kwong HC

PROVIDER: S-EPMC3247400 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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4-(Dodec-yloxy)benzonitrile.

Kwong Huey Chong HC Rahman Mohamad Zaki Ab MZ Mohamed Tahir Mohamed Ibrahim MI Silong Sidik S

Acta crystallographica. Section E, Structure reports online 20111022 Pt 11

In the title compound, C(19)H(29)NO, the C-C and C-N bond distances of the benzonitrile group are 1.445 (2) and 1.157 (2) Å, respectively. The aliphatic fragment adopts a bent zigzag arangement which differs from the planar zigzag arrangement normally observed in n-alkanes or long-chain alkyl-benzenes. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds occur. A C-H⋯N inter-action also occurs. In the crystal, mol-ecules are packed with the nitrile and aliphatic groups orient ...[more]

PMID: 22220018

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