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Benzyl (E)-3-(4-meth-oxy-benzyl-idene)dithio-carbazate.

ABSTRACT: The title compound, C(16)H(16)N(2)OS(2), was obtained from a condensation reaction of benzyl dithio-carbazate and 4-meth-oxy-benzaldehyde. In the mol-ecule, the meth-oxy-phenyl ring and dithio-carbazate fragment are located on opposite sides of the C=N double bond, showing an E configuration. The dithio-carbazate fragment is approximately planar (r.m.s. deviation = 0.0052?Å); its mean plane is oriented at dihedral angles of 8.19?(15) and 85.70?(13)°, respectively, to the meth-oxy-phenyl and phenyl rings. Inter-molecular N-H?S hydrogen bonds and weak C-H?? inter-actions are observed in the crystal structure.

SUBMITTER: Fan Z

PROVIDER: S-EPMC3247410 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Benzyl (E)-3-(4-meth-oxy-benzyl-idene)dithio-carbazate.

Fan Zheng Z Huang Yan-Lan YL Wang Zhao Z Guo Han-Qi HQ Shan Shang S

Acta crystallographica. Section E, Structure reports online 20111022 Pt 11

The title compound, C(16)H(16)N(2)OS(2), was obtained from a condensation reaction of benzyl dithio-carbazate and 4-meth-oxy-benzaldehyde. In the mol-ecule, the meth-oxy-phenyl ring and dithio-carbazate fragment are located on opposite sides of the C=N double bond, showing an E configuration. The dithio-carbazate fragment is approximately planar (r.m.s. deviation = 0.0052 Å); its mean plane is oriented at dihedral angles of 8.19 (15) and 85.70 (13)°, respectively, to the meth-oxy-phenyl and phen ...[more]

PMID: 22220028

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