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Benzyl (E)-3-(2-bromo-5-meth-oxy-benzyl-idene)dithio-carbazate.

ABSTRACT: The title compound, C(16)H(15)BrN(2)OS(2), was obtained from the condensation reaction of benzyl dithio-carbazate and 2-bromo-5-meth-oxy-lbenzaldehyde. In the mol-ecule, the bromo-meth-oxy-phenyl ring and dithio-carbazate fragment are located on the opposite sides of the C=N double bond, showing the E conformation. The dithio-carbazate fragment is approximately planar (r.m.s deviation 0.0187?Å); its mean plane is oriented with respect to the bromo-meth-oxy-phenyl and phenyl rings at 7.60?(12) and 60.08?(9)°, respectively. In the crystal, inversion dimers linked by pairs of N-H?S hydrogen bonds occur. A short Br?Br contact of 3.5526?(12)?Å is observed in the crystal structure.

SUBMITTER: Fan Z

PROVIDER: S-EPMC3247414 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Benzyl (E)-3-(2-bromo-5-meth-oxy-benzyl-idene)dithio-carbazate.

Fan Zheng Z Huang Yan-Lan YL Wang Zhao Z Guo Han-Qi HQ Shan Shang S

Acta crystallographica. Section E, Structure reports online 20111022 Pt 11

The title compound, C(16)H(15)BrN(2)OS(2), was obtained from the condensation reaction of benzyl dithio-carbazate and 2-bromo-5-meth-oxy-lbenzaldehyde. In the mol-ecule, the bromo-meth-oxy-phenyl ring and dithio-carbazate fragment are located on the opposite sides of the C=N double bond, showing the E conformation. The dithio-carbazate fragment is approximately planar (r.m.s deviation 0.0187 Å); its mean plane is oriented with respect to the bromo-meth-oxy-phenyl and phenyl rings at 7.60 (12) an ...[more]

PMID: 22220032

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