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Meso-3,6-Dioxopiperazine-2,5-diacet-amide.

ABSTRACT: The title compound, C(8)H(12)N(4)O(4), was obtained by cyclization of the two l-asparagine mol-ecules and reveals a crystallographic inversion symmetry, and accordingly the two stereogenic centres are of opposite chirality. Thus, an asymmetric unit comprises a half of a mol-ecule. The mol-ecules are assembled into a three-dimensional hydrogen-bonding network by N-H?O hydrogen bonds.

SUBMITTER: Li P

PROVIDER: S-EPMC3247435 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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meso-3,6-Dioxopiperazine-2,5-diacet-amide.

Li Ping P Zhang Chun C Xu Wei W

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

The title compound, C(8)H(12)N(4)O(4), was obtained by cyclization of the two l-asparagine mol-ecules and reveals a crystallographic inversion symmetry, and accordingly the two stereogenic centres are of opposite chirality. Thus, an asymmetric unit comprises a half of a mol-ecule. The mol-ecules are assembled into a three-dimensional hydrogen-bonding network by N-H⋯O hydrogen bonds. ...[more]

PMID: 22220053

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