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Fac-Tricarbon-yl(pyridine-?N)(1,1,1-trifluoro-acetyl-acetonato-?O,O')rhenium(I).

ABSTRACT: In the title compound, [Re(C(5)H(4)F(3)O(2))(C(5)H(5)N)(CO)(3)], the Re(I) atom is six-coordinated owing to bonding by three carbonyl ligands arranged in a fac configuration, two O atoms from the bidentate 1,1,1-trifluoro-acetyl-acetonate ligand and an N atom from a pyridine ligand. In the crystal, the mol-ecules pack in layers, diagonally, in a head-to-tail fashion across the ab plane. These layers are stabilsed by inter-molecular C-H?O and C-H?F hydrogen bonds.

SUBMITTER: Visser HG

PROVIDER: S-EPMC3247548 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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fac-Tricarbon-yl(pyridine-κN)(1,1,1-trifluoro-acetyl-acetonato-κO,O')rhenium(I).

Visser Hendrik G HG Roodt Andreas A Volmink Amanda-Lee AL Kemp Gerdus G

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

In the title compound, [Re(C(5)H(4)F(3)O(2))(C(5)H(5)N)(CO)(3)], the Re(I) atom is six-coordinated owing to bonding by three carbonyl ligands arranged in a fac configuration, two O atoms from the bidentate 1,1,1-trifluoro-acetyl-acetonate ligand and an N atom from a pyridine ligand. In the crystal, the mol-ecules pack in layers, diagonally, in a head-to-tail fashion across the ab plane. These layers are stabilsed by inter-molecular C-H⋯O and C-H⋯F hydrogen bonds. ...[more]

PMID: 22219853

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