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N'-(4-Fluoro-benzyl-idene)-2-(4-fluoro-phen-yl)acetohydrazide.

ABSTRACT: In the title compound, C(15)H(12)F(2)N(2)O, the dihedral angle between the two benzene rings is 48.73?(8)°. The hydrazine group is twisted slightly, with a C-N-N-C torsion angle of 172.48?(12)°. In the crystal, mol-ecules are connected by strong N-H?O and weak C-H?O hydrogen bonds, forming supra-molecular chains along the c axis. The structure is consolidated by ?-? [centroid-centroid separation = 3.6579?(10)?Å] and C-H?? inter-actions.

SUBMITTER: Fun HK 

PROVIDER: S-EPMC3247574 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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N'-(4-Fluoro-benzyl-idene)-2-(4-fluoro-phen-yl)acetohydrazide.

Fun Hoong-Kun HK   Hemamalini Madhukar M   Sumangala V V   Nagaraja G K GK   Poojary Boja B  

Acta crystallographica. Section E, Structure reports online 20111005 Pt 11

In the title compound, C(15)H(12)F(2)N(2)O, the dihedral angle between the two benzene rings is 48.73 (8)°. The hydrazine group is twisted slightly, with a C-N-N-C torsion angle of 172.48 (12)°. In the crystal, mol-ecules are connected by strong N-H⋯O and weak C-H⋯O hydrogen bonds, forming supra-molecular chains along the c axis. The structure is consolidated by π-π [centroid-centroid separation = 3.6579 (10) Å] and C-H⋯π inter-actions. ...[more]

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