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N-{4-[(3-Methyl-phen-yl)sulfamo-yl]phen-yl}benzamide.

ABSTRACT: In the title compound, C(20)H(18)N(2)O(3)S, the dihedral angle between the central benzene ring and the amide group is 24.1?(3)° and that between this ring and the aromatic ring of the tolyl group is 68.2?(16)°. In the crystal, adjacent mol-ecules are linked by N-H?O hydrogen bonds into a linear chain running along [100]. Weak C-H?O contacts also occur. Extensive weak ?-? inter-actions exist from both face-to-face and face-to-edge inter-actions occur between the aromatic rings [centroid-centroid distances = 3.612?(2) and 4.843?(2)?Å].

SUBMITTER: Lahtinen M

PROVIDER: S-EPMC3247601 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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N-{4-[(3-Methyl-phen-yl)sulfamo-yl]phen-yl}benzamide.

Lahtinen Manu M Damodara Jyothi J Upadhyaya Poornima P Nonappa Kolehmainen Erkki E

Acta crystallographica. Section E, Structure reports online 20111008 Pt 11

In the title compound, C(20)H(18)N(2)O(3)S, the dihedral angle between the central benzene ring and the amide group is 24.1 (3)° and that between this ring and the aromatic ring of the tolyl group is 68.2 (16)°. In the crystal, adjacent mol-ecules are linked by N-H⋯O hydrogen bonds into a linear chain running along [100]. Weak C-H⋯O contacts also occur. Extensive weak π-π inter-actions exist from both face-to-face and face-to-edge inter-actions occur between the aromatic rings [centroid-centroid ...[more]

PMID: 22219906

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N-{4-[(5-Methyl-isoxazol-3-yl)sulfamo-yl]phen-yl}benzamide.

Project description:In the title compound, C(17)H(15)N(3)O(4)S, the five-membered isoxazole ring makes dihedral angles of 80.5 (2) and 81.3 (2)° with the two benzene rings, which form a dihedral angle of 39.81 (18)° with each other. A short intra-molecular C-H⋯O contact occurs. The crystal structure is stabilized by inter-molecular N-H⋯O hydrogen bonds, which generate [001] chains, and further consolidated by weak C-H⋯O inter-actions.

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