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Rhodium-catalyzed intramolecular C-H insertion of alpha-aryl-alpha-diazo ketones.

ABSTRACT: Direct diazo transfer proceeds smoothly with alpha-aryl ketones. The derived alpha-aryl-alpha-diazo ketones cyclize efficiently with Rh catalysis to give the corresponding alpha-aryl cyclopentanones.

SUBMITTER: Taber DF 

PROVIDER: S-EPMC3248813 | biostudies-literature | 2007 Apr

REPOSITORIES: biostudies-literature

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Rhodium-catalyzed intramolecular C-H insertion of alpha-aryl-alpha-diazo ketones.

Taber Douglass F DF   Tian Weiwei W  

The Journal of organic chemistry 20070327 9

Direct diazo transfer proceeds smoothly with alpha-aryl ketones. The derived alpha-aryl-alpha-diazo ketones cyclize efficiently with Rh catalysis to give the corresponding alpha-aryl cyclopentanones. ...[more]

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