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(3-{[N-(5-Chloro-2-hy-droxy-phen-yl)oxamo-yl]amino}-prop-yl)dimethyl-aza-nium perchlorate.

ABSTRACT: In the title compound, C(13)H(19)ClN(3)O(3) (+)·ClO(4) (-), the 3-(di-meth-yl-ammonio)-propyl group of the cation is disordered over two sets of sites with occupancies 0.772?(6) and 0.228?(6). The cations are joined by pairs of N-H?O hydrogen bonds into centrosymmetric dimers and these dimers are assembled into chains along the a-axis direction, also through N-H?O hydrogen bonds. The perchlorate anions are linked to the hy-droxy groups of the cations by O-H?O hydrogen bonds. The positively charged ammonium groups and the anions give rise to folded layers parallel to the ab plane.

SUBMITTER: Yue XT

PROVIDER: S-EPMC3254288 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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(3-{[N-(5-Chloro-2-hy-droxy-phen-yl)oxamo-yl]amino}-prop-yl)dimethyl-aza-nium perchlorate.

Yue Xi-Teng XT Li Xiao-Wen XW Wu Zhi-Yong ZY

Acta crystallographica. Section E, Structure reports online 20111203 Pt 1

In the title compound, C(13)H(19)ClN(3)O(3) (+)·ClO(4) (-), the 3-(di-meth-yl-ammonio)-propyl group of the cation is disordered over two sets of sites with occupancies 0.772 (6) and 0.228 (6). The cations are joined by pairs of N-H⋯O hydrogen bonds into centrosymmetric dimers and these dimers are assembled into chains along the a-axis direction, also through N-H⋯O hydrogen bonds. The perchlorate anions are linked to the hy-droxy groups of the cations by O-H⋯O hydrogen bonds. The positively charg ...[more]

PMID: 22259579

Similar Datasets

2,5-Bis[2-({bis-[3-(dimethyl-aza-nium-yl)prop-yl]aza-nium-yl}meth-yl)phen-yl]-1,3,4-oxadiazole hexa-kis-(perchlorate) sesquihydrate.

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Ethyl [(benzyl-aza-nium-yl)(2-hy-droxy-phen-yl)meth-yl]phospho-nate.

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Project description:In the title compound, C(14)H(21)N(3)O(3), the oxamide group has a transoid conformation. In the crystal, the mol-ecules are connected by N-H⋯O and O-H⋯N hydrogen bonds into a double chain running along the b axis.

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rac-4-Chloro-2-[({2-[(3-chloro-6-hy-droxy-2,4-dimethyl-benz-yl)(meth-yl)amino]-prop-yl}(meth-yl)amino)-meth-yl]-3,5-dimethyl-phenol.

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