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Methyl (2Z)-2-({N-[2-(hy-droxy-meth-yl)phen-yl]-4-methyl-benzene-sulfonamido}-meth-yl)-3-phenyl-prop-2-enoate.

ABSTRACT: In the title compound, C(25)H(25)NO(5)S, the O atom of the hy-droxy group is disordered over two positions, with occupancies of 0.820?(2) and 0.180?(2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8?(1) and 60.7?(1)°, respectively, with the hy-droxy-methyl-benzene and phenyl rings. The mol-ecular conformation is stabilized by an intra-molecular O-H?O hydrogen bond, generating an S(8) ring motif. The crystal packing is stabilized by inter-molecular C-H?O hydrogen bonds and C-H?? inter-actions.

SUBMITTER: Madhanraj R

PROVIDER: S-EPMC3275177 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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Methyl (2Z)-2-({N-[2-(hy-droxy-meth-yl)phen-yl]-4-methyl-benzene-sulfonamido}-meth-yl)-3-phenyl-prop-2-enoate.

Madhanraj R R Murugavel S S Kannan D D Bakthadoss M M

Acta crystallographica. Section E, Structure reports online 20120114 Pt 2

In the title compound, C(25)H(25)NO(5)S, the O atom of the hy-droxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hy-droxy-methyl-benzene and phenyl rings. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯O hydrogen bond, generating an S(8) ring motif. The crystal packing is stabilized by inter-molecular C-H⋯O hydrogen bonds and C-H⋯π i ...[more]

PMID: 22347033

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