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Methyl (2Z)-2-[(2-formyl-3-methyl-1H-indol-1-yl)meth-yl]-3-(4-meth-oxy-phen-yl)prop-2-enoate.

ABSTRACT: In the title indole derivative, C22H21NO4, the dihedral angle between the benzene and pyrrole rings of indole moiety is 1.8?(1)°. The plane of the 4-meth-oxy-phenyl ring is oriented with a dihedral angle of 60.7?(1)° with respect to the plane of the indole moiety. The mol-ecular packing is stabilized by C-H?O hydrogen bonds which form a V-shaped chain arrangement along the bc plane of the unit cell. In addition to this, C-H?? and ?-? inter-actions [centroid-centroid distances = 3.8102?(11) and 3.8803(12)?Å], which run along the b-axis direction, stabilize the mol-ecular packing.

SUBMITTER: Selvanayagam S

PROVIDER: S-EPMC3998543 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature

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Methyl (2Z)-2-[(2-formyl-3-methyl-1H-indol-1-yl)meth-yl]-3-(4-meth-oxy-phen-yl)prop-2-enoate.

Selvanayagam S S Sridhar B B Kathiravan S S Raghunathan R R

Acta crystallographica. Section E, Structure reports online 20140315 Pt 4

In the title indole derivative, C22H21NO4, the dihedral angle between the benzene and pyrrole rings of indole moiety is 1.8 (1)°. The plane of the 4-meth-oxy-phenyl ring is oriented with a dihedral angle of 60.7 (1)° with respect to the plane of the indole moiety. The mol-ecular packing is stabilized by C-H⋯O hydrogen bonds which form a V-shaped chain arrangement along the bc plane of the unit cell. In addition to this, C-H⋯π and π-π inter-actions [centroid-centroid distances = 3.8102 (11) and 3 ...[more]

PMID: 24826139

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