Ontology highlight
ABSTRACT:
SUBMITTER: Michaudel Q
PROVIDER: S-EPMC3277284 | biostudies-literature | 2012 Feb
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20120127 5
Intermolecular Ritter-type C-H amination of unactivated sp(3) carbons has been developed. This new reaction proceeds under mild conditions using readily available reagents and an inexpensive source of nitrogen (acetonitrile). A broad scope of substrates can be aminated with this method since many functional groups are tolerated. This reaction also allows for the direct, innate C-H amination of a variety of hydrocarbons such as cyclohexane without the need of prefunctionalization or installation ...[more]