Ontology highlight
ABSTRACT:
SUBMITTER: Baranczak A
PROVIDER: S-EPMC3292050 | biostudies-literature | 2012 Feb
REPOSITORIES: biostudies-literature
Baranczak Aleksandra A Sulikowski Gary A GA
Organic letters 20120206 4
In the course of studies directed toward the synthesis of dideoxy lomaiviticinone, 3-(nitromethyl)cyclohexenones 2a (X = H) and 2b (X = I) were prepared. The corresponding enolates were reacted with naphthazarin (1) and unexpectedly afforded 1,2-oxazepine 3 and isoxazole 4, respectively. Rationale for their formation is proposed. ...[more]