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N-Heterocyclic Carbene-Promoted Rauhut]Currier Reactions between Vinyl Sulfones and ?,?-Unsaturated Aldehydes.

ABSTRACT: N-heterocyclic carbenes (NHCs) promote the addition of 1,1-bis(phenylsulfonyl)ethylene to the ?-position of ?,?-unsaturated aldehydes. The proposed reaction pathway for this Rauhut-Currier-type reaction includes an unusual conjugate addition of an NHC to a bis-vinyl sulfone.

SUBMITTER: Atienza RL 

PROVIDER: S-EPMC3293187 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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N-Heterocyclic Carbene-Promoted Rauhut]Currier Reactions between Vinyl Sulfones and α,β-Unsaturated Aldehydes.

Atienza Roxanne L RL   Scheidt Karl A KA  

Australian journal of chemistry 20110801 8

N-heterocyclic carbenes (NHCs) promote the addition of 1,1-bis(phenylsulfonyl)ethylene to the α-position of α,β-unsaturated aldehydes. The proposed reaction pathway for this Rauhut-Currier-type reaction includes an unusual conjugate addition of an NHC to a bis-vinyl sulfone. ...[more]

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