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?(3)-Chlorido-tris-(bis-{1-[2-(dimethyl-amino)-eth-yl]-3-methyl-imidazol-2-yl-idene}silver(I)) dichloride.

ABSTRACT: In the crystal structure of the title compound, [Ag(3)Cl(C(8)H(15)N(3))(6)]Cl(2), the Ag(I) ion, which is located on a twofold rotation axis, exists in a T-shape coordination environment. Two carbene C atoms of the N-heterocyclic carbene (NHC) ligands are bonded tightly forming a slightly bent [Ag(NHC)(2)](+) cation [C-Ag-C angle = 162.80?(18)°]. Three of these complex cations are further aggregated by one bridging chloride anion, which is lying on a threefold rotoinversion axis and is only loosely binding to the Ag(+) ions. The N atom of the amine group is not engaged in any coordinative bond.

SUBMITTER: Topf C

PROVIDER: S-EPMC3297232 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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μ(3)-Chlorido-tris-(bis-{1-[2-(dimethyl-amino)-eth-yl]-3-methyl-imidazol-2-yl-idene}silver(I)) dichloride.

Topf Christoph C Leitner Sebastian S Monkowius Uwe U

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

In the crystal structure of the title compound, [Ag(3)Cl(C(8)H(15)N(3))(6)]Cl(2), the Ag(I) ion, which is located on a twofold rotation axis, exists in a T-shape coordination environment. Two carbene C atoms of the N-heterocyclic carbene (NHC) ligands are bonded tightly forming a slightly bent [Ag(NHC)(2)](+) cation [C-Ag-C angle = 162.80 (18)°]. Three of these complex cations are further aggregated by one bridging chloride anion, which is lying on a threefold rotoinversion axis and is only loos ...[more]

PMID: 22412422

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