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Bis[4-amino-N-(pyrimidin-2-yl-?N)benzene-sulfonamidato-?N](4,4'-di-methyl-2,2'-bipyridine-?N,N')cadmium dimethyl-formamide disolvate.

ABSTRACT: In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal-prismatic geometry arising from the two sulfadiazinate ligands and one 4,4'-dimethyl-2,2'-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethyl-formamide mol-ecule show disorder and were modelled with two different orientations and with site occupancies of 0.584?(10):0.416?(10). The geometry around the sulfadiazine S atom is distorted tetra-hedral. The crystal structure involves N-H?O hydrogen bonds which link mol-ecules into a three-dimensional network. Weak C-H?O hydrogen bonds are also observed.

SUBMITTER: Hossain GM 

PROVIDER: S-EPMC3297235 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Bis[4-amino-N-(pyrimidin-2-yl-κN)benzene-sulfonamidato-κN](4,4'-di-methyl-2,2'-bipyridine-κN,N')cadmium dimethyl-formamide disolvate.

Hossain G M Golzar GM   Amoroso A J AJ  

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal-prismatic geometry arising from the two sulfadiazinate ligands and one 4,4'-dimethyl-2,2'-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethyl-formamide mol-ecule show disorder and were modelled with two different orientations and with site occupa  ...[more]

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