Unknown

Dataset Information

0

Diaqua-(5-carb-oxy-benzene-1,3-di-carboxyl-ato-?O)(4,4'-dimethyl-2,2'-bipyridine-?N,N')zinc.


ABSTRACT: In the title compound, [Zn(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)], the Zn(II) atom is five-coordinated by two N atoms from a 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a 5-carb-oxy-benzene-1,3-dicarboxyl-ate ligand and two water mol-ecules in a distorted trigonal-bipyramidal geometry. The complex mol-ecules are linked by inter-molecular O-H?O hydrogen bonds and partly overlapping ?-? inter-actions [centroid-centroid distance = 4.017?(2)?Å] into a three-dimensional supra-molecular network.

SUBMITTER: Mei CZ 

PROVIDER: S-EPMC3120513 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

altmetric image

Publications

Diaqua-(5-carb-oxy-benzene-1,3-di-carboxyl-ato-κO)(4,4'-dimethyl-2,2'-bipyridine-κN,N')zinc.

Mei Chong-Zhen CZ   Li Kai-Hui KH   Shan Wen-Wen WW  

Acta crystallographica. Section E, Structure reports online 20110528 Pt 6


In the title compound, [Zn(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)], the Zn(II) atom is five-coordinated by two N atoms from a 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a 5-carb-oxy-benzene-1,3-dicarboxyl-ate ligand and two water mol-ecules in a distorted trigonal-bipyramidal geometry. The complex mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds and partly overlapping π-π inter-actions [centroid-centroid distance = 4.017 (2) Å] into a three-dimensional supra-molecular ne  ...[more]

Similar Datasets

| S-EPMC3200942 | biostudies-literature
| S-EPMC2915173 | biostudies-literature
| S-EPMC2961716 | biostudies-literature
| S-EPMC3297246 | biostudies-literature
| S-EPMC3051434 | biostudies-literature
| S-EPMC2971185 | biostudies-literature
| S-EPMC3052002 | biostudies-literature
| S-EPMC3120548 | biostudies-literature
| S-EPMC2968579 | biostudies-literature
| S-EPMC2959485 | biostudies-literature