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Bis[N-(2-hy-droxy-eth-yl)-N-methyl-dithio-carbamato-?S][2,4,6-tris-(pyridin-2-yl)-1,3,5-triazine-?N,N,N]zinc dioxane sesquisolvate.

ABSTRACT: The asymmetric unit of the title compound, [Zn(C(4)H(8)NOS(2))(2)(C(18)H(12)N(6))]·1.5C(4)H(8)O(2), comprises a Zn-containing mol-ecule and one and a half dioxane mol-ecules as one of the solvent mol-ecules is located about a crystallographic inversion centre. The approximately square-pyramidal N(3)S(2) donor set is defined by two monodentate dithio-carbamate ligands and two pyridine and one triazine N atom from the tridentate triazine ligand. Mol-ecules are connected into a supra-molecular array via O-H?S and O-H?N hydrogen bonds. These stack along the b axis and the solvent mol-ecules reside in the channels thus formed.

SUBMITTER: Arman HD

PROVIDER: S-EPMC3297268 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Bis[N-(2-hy-droxy-eth-yl)-N-methyl-dithio-carbamato-κS][2,4,6-tris-(pyridin-2-yl)-1,3,5-triazine-κN,N,N]zinc dioxane sesquisolvate.

Arman Hadi D HD Poplaukhin Pavel P Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20120224 Pt 3

The asymmetric unit of the title compound, [Zn(C(4)H(8)NOS(2))(2)(C(18)H(12)N(6))]·1.5C(4)H(8)O(2), comprises a Zn-containing mol-ecule and one and a half dioxane mol-ecules as one of the solvent mol-ecules is located about a crystallographic inversion centre. The approximately square-pyramidal N(3)S(2) donor set is defined by two monodentate dithio-carbamate ligands and two pyridine and one triazine N atom from the tridentate triazine ligand. Mol-ecules are connected into a supra-molecular arra ...[more]

PMID: 22412458

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