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Seven-coordinate anion complex with a tren-based urea: binding discrepancy of hydrogen sulfate in solid and solution states.


ABSTRACT: Structural characterization of a hydrogen sulfate complex with a tren-based urea suggests that the anion is coordinated with six NH···O bonds (d(N···O) = 2.857 (3) to 3.092 (3) Å) and one OH···O bond (d(O···O) = 2.57 (2) Å) from three receptors; however, in solution the anion is bound within the pseudo-cavity of one receptor.

SUBMITTER: Pramanik A 

PROVIDER: S-EPMC3306551 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Seven-coordinate anion complex with a tren-based urea: binding discrepancy of hydrogen sulfate in solid and solution states.

Pramanik Avijit A   Thompson Bethtrice B   Hayes Trina T   Tucker Kimberly K   Powell Douglas R DR   Bonnesen Peter V PV   Ellis Erick D ED   Lee Ken S KS   Yu Hongtao H   Hossain Md Alamgir MA  

Organic & biomolecular chemistry 20110321 12


Structural characterization of a hydrogen sulfate complex with a tren-based urea suggests that the anion is coordinated with six NH···O bonds (d(N···O) = 2.857 (3) to 3.092 (3) Å) and one OH···O bond (d(O···O) = 2.57 (2) Å) from three receptors; however, in solution the anion is bound within the pseudo-cavity of one receptor. ...[more]

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