Ontology highlight
ABSTRACT:
SUBMITTER: DeKorver KA
PROVIDER: S-EPMC3321125 | biostudies-literature | 2012 Apr
REPOSITORIES: biostudies-literature
DeKorver Kyle A KA Wang Xiao-Na XN Walton Mary C MC Hsung Richard P RP
Organic letters 20120313 7
A series of carbocyclization cascades of allyl ketenimines initiated through a thermal aza-Claisen rearrangement of N-phosphoryl-N-allyl ynamides is described. Interceptions of the cationic intermediate via Meerwein-Wagner rearrangements and polyene-type cyclizations en route to fused bi- and tricyclic frameworks are featured. ...[more]