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N,N-Dimethyl-4-[(E)-2-(3,6,7-tribromo-9-butyl-9H-carbazol-2-yl)ethen-yl]aniline.

ABSTRACT: In the title mol-ecule, C(26)H(25)Br(3)N(2), a dihedral angle of 6.15?(10)° is present between the carbazole and benzene ring systems with an E conformation about the C=C bond [1.335?(4)?Å]. The butyl group is almost perpendicular to the carbazole plane [C-N-C-C torsion angle = -98.7?(3)°]. In the crystal, supra-molecular double chains along [-7,18,-16] are formed via C-H?Br and ?-? inter-actions [centroid(carbazole five-membered ring)?centroid(carbazole six-membered ring) distance = 3.6333?(13)?Å].

SUBMITTER: Kumar S

PROVIDER: S-EPMC3344067 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

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N,N-Dimethyl-4-[(E)-2-(3,6,7-tribromo-9-butyl-9H-carbazol-2-yl)ethen-yl]aniline.

Kumar Sushil S Thomas K R Justin KR Ng Seik Weng SW Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20120321 Pt 4

In the title mol-ecule, C(26)H(25)Br(3)N(2), a dihedral angle of 6.15 (10)° is present between the carbazole and benzene ring systems with an E conformation about the C=C bond [1.335 (4) Å]. The butyl group is almost perpendicular to the carbazole plane [C-N-C-C torsion angle = -98.7 (3)°]. In the crystal, supra-molecular double chains along [-7,18,-16] are formed via C-H⋯Br and π-π inter-actions [centroid(carbazole five-membered ring)⋯centroid(carbazole six-membered ring) distance = 3.6333 (13) ...[more]

PMID: 22589976

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