Browse
Submit Data
Databases
API
Help

Dataset Information

23 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

4-{2-[(E)-Cyclo-pentyl-idene]hydrazin-1-yl}benzene-sulfonamide.

ABSTRACT: The title mol-ecule, C(11)H(15)N(3)O(2)S, features a five-membered ring which is twisted about the middle CH(2)-CH(2) bond. The benzene ring is inclined with respect to the imine residue [C-N-N-C torsion angle = 165.4?(2)°]. Supra-molecular layers in the bc plane are formed by hydrogen bonds between the amine H atoms and sulfonamide O and imine N atoms, as well as by a weak hydrazine H-atom inter-molecular inter-action with the second sulfonamide O atom.

SUBMITTER: Al-Youbi AO

PROVIDER: S-EPMC3344133 | biostudies-literature | 2012 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

4-{2-[(E)-Cyclo-pentyl-idene]hydrazin-1-yl}benzene-sulfonamide.

Al-Youbi Abdulrahman O AO Asiri Abdullah M AM Faidallah Hassan M HM Ng Seik Weng SW Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20120328 Pt 4

The title mol-ecule, C(11)H(15)N(3)O(2)S, features a five-membered ring which is twisted about the middle CH(2)-CH(2) bond. The benzene ring is inclined with respect to the imine residue [C-N-N-C torsion angle = 165.4 (2)°]. Supra-molecular layers in the bc plane are formed by hydrogen bonds between the amine H atoms and sulfonamide O and imine N atoms, as well as by a weak hydrazine H-atom inter-molecular inter-action with the second sulfonamide O atom. ...[more]

PMID: 22606136

Similar Datasets

3-Chloro-6-[2-(cyclo-pentyl-idene)hydrazin-1-yl]pyridazine.

Project description:The asymmetric unit of the title compound, C(9)H(11)ClN(4), contains two virtually planar mol-ecules that differ in conformation about the bond connecting the hydrazine and pyridazine units. The 3-chloro-6-hydrazinylpyridazine and cyclo-pentane groups are oriented at dihedral angles of 4.5?(3) and 8.8?(4)° in the two mol-ecules. In the crystal, the mol-ecules form a one dimensional polymeric structure extending along the a axis via N-H?N hydrogen bonds. The crystal stucired was an inversion twin [ratio of the twin domains = 0.73?(9):0.27?(9)].

| S-EPMC3099815 | biostudies-other

(2E)-4-(4-Bromo-phen-yl)-2-{2-[(1E)-cyclo-pentyl-idene]hydrazin-1-yl-idene}-3-phenyl-2,3-di-hydro-1,3-thia-zole.

Project description:In the title compound, C20H18BrN3S, the cyclo-pentane ring adopts a half-chair conformation. The 4-bromo-phenyl and phenyl rings make dihedral angles of 34.6?(1) and 68.52?(6)°, respectively, with the di-hydro-thia-zole ring. In the crystal, the mol-ecules pack in sheets approximately parallel to (101) which are formed by weak C-H?Br inter-actions.

| S-EPMC4051030 | biostudies-literature

2-(N-Cyclo-hexyl-carbamo-yl)benzene-sulfonamide.

Project description:The asymmetric unit of the title compound, C(13)H(18)N(2)O(3)S, contains two mol-ecules with similar conformations. In both mol-ecules, the cyclo-hexyl rings adopt chair conformations, with the attached N atom in an equatorial orientation and an intra-molecular N-H?O hydrogen bond generates an S(7) ring. In the crystal, N-H?O hydrogen bonds link the mol-ecules and a C-H?O hydrogen bond is also observed. The crystal studied was a racemic twin.

| S-EPMC3275049 | biostudies-literature

Crystal structure of (E)-N-{2-[2-(3-chloro-benzyl-idene)hydrazin-yl]-2-oxoeth-yl}-4-methyl-benzene-sulfonamide monohydrate.

Project description:The mol-ecule of the title compound, C16H16ClN3O3S·H2O, is L-shaped being bent at the S atom; the S-N-C-C torsion angle is 132.0?(3)°. The central part of the mol-ecule, C-C-N-N=C, is almost linear, with the C-C-N-N and C-N-N=C torsion angles being -174.1?(2) and 176.0?(2)°, respectively. The dihedral angle between the p-toluene-sulfonyl ring and the S-N-C-C(=O) segment is 67.5?(4)°, while that between the two aromatic rings is 52.17?(11)°. In the crystal, the water H atom is involved in O-H?O hydrogen bonds with a sulfonamide O atom and the carbonyl O atom. The water O atom is itself hydrogen bonded to both NH hydrogen atoms. These four hydrogen bonds lead to the formation of corrugated sheets lying parallel to (100). There are also weak C-H?O contacts present within the sheets.

| S-EPMC4459383 | biostudies-literature

N-Cyclo-hexyl-4-meth-yl-N-propyl-benzene-sulfonamide.

Project description:The title compound, C(16)H(25)NO(2)S, is a sulfonamide derivative with the substitution of propyl and cyclo-hexyl groups at the N atom. The least-squares plane through all six C atoms of the cyclo-hexyl ring forms a dihedral angle of 58.88?(12)° with the toluene ring. No hydrogen-bonding inter-actions are present in the crystal structure.

| S-EPMC2983795 | biostudies-literature

N-Cyclo-hexyl-N-(prop-2-en-1-yl)benzene-sulfonamide.

Project description:The title compound, C(15)H(21)NO(2)S, synthesized by N-alkyl-ation of cyclo-hexyl-amine benzene-sulfonamide with allyl iodide, is of inter-est as a precursor to biologically active sulfur-containing heterocyclic compounds. The cyclo-hexane ring is in a chair form and its mean plane makes a dihedral angle of 53.84?(12)° with the phenyl ring.

| S-EPMC2972124 | biostudies-literature

2-{(E)-1-[2-(4-Nitro-phen-yl)hydrazin-1-yl-idene]eth-yl}benzene-1,3-diol.

Project description:The title compound, C(14)H(13)N(3)O(4), is close to planar, the dihedral angle between the terminal benzene rings being 5.80?(16)°; the nitro group is coplanar with the benzene ring to which it is bonded [O-N-C-C torsion angle = -177.3?(3)°]. The hy-droxy group forms an intra-molecular hydrogen bond with the imine N atom, and the conformation about the imine bond is E. In the crystal, layers in the (101) plane with an undulating topology are formed by O-H?O and N-H?O hydrogen bonds along with C-H?O inter-actions. Centrosymmetrically related layers are connected via ?-? inter-actions [ring centroid-centroid distance = 3.5739?(19)?Å] into double layers.

| S-EPMC3295468 | biostudies-literature

Crystal structure of (E)-4-methyl-N-{2-[2-(4-nitro-benzyl-idene)hydrazin-1-yl]-2-oxoeth-yl}benzene-sulfonamide N,N-di-methyl-formamide monosolvate.

Project description:The mol-ecule of the title Schiff base compound, C16H16N4O5S·C3H7NO, displays a trans conformation with respect to the C=N double bond. The C-N and N-N bonds are relatively short compared to their normal bond lengths, indicating some degree of delocalization in the mol-ecule. The mol-ecule is bent at the S atom, with an S-N-C-C torsion angle of 164.48?(11)°. The dihedral angle between the two aromatic rings is 84.594?(7)°. Inter-molecular N-H?O and C -H?O hydrogen bonds connect centrosymmetrically related mol-ecules into dimers forming rings of R33(11) and R22(10) graph-set motif stacked along the a axis into a columnar arrangement. The mol-ecular columns are further linked into a three-dimensional network by C-H?? inter-actions.

| S-EPMC5683490 | biostudies-literature

N'-Cyclo-pentyl-idene-pyridine-4-carbo-hydrazide.

Project description:The title compound, C(11)H(13)N(3)O, is a derivative of the anti-tuberculosis drug isoniazid [systematic name: pyridine-4-carbohydrazide]. The crystal structure consists of repeating hydrogen-bonded chains parallel to the b axis. Adjacent mol-ecules in the chains are linked by bifurcated N-H?(O,N) hydrogen bonds, which form an R(1) (2)(5) ring motif.

| S-EPMC3344445 | biostudies-literature

4-{2-[(Z)-(5-Methyl-2-fur-yl)methyl-idene-amino]-eth-yl}benzene-sulfonamide.

Project description:In the title compound, C(14)H(16)N(2)O(3)S, the dihedral angle between the phenyl and 5-methyl-furan groups is 54.89 (14)° and the C=N bond assumes a trans conformation. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) ring motifs. The dimers are inter-linked by N-H⋯N hydrogen bonds, resulting in the formation of infinite chains extending along the b axis. The packing is consolidated by weak C-H⋯π inter-actions.

| S-EPMC3008043 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data