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{S-Benzyl 3-[(6-methyl-pyridin-2-yl-?N)methyl-idene]dithio-carbazato-?(2)N(3),S}zinc.

ABSTRACT: The title compound, [Zn(C(15)H(14)N(3)S(2))(2)], contains two chemically equivalent Schiff base anions that are coordinated to the Zn(II) ion as tridentate N,N',S-chelating ligands, creating a distorted octa-hedral environment [the smallest angle being 75.40?(6)° and the widest angle being 162.87?(6)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 85.65?(5)°. Weak C-H?S hydrogen bonds are also observed.

SUBMITTER: Ravoof TB

PROVIDER: S-EPMC3344295 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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{S-Benzyl 3-[(6-methyl-pyridin-2-yl-κN)methyl-idene]dithio-carbazato-κ(2)N(3),S}zinc.

Ravoof Thahira B S A TB Omar Siti Aminah SA Mohamed Tahir Mohamed Ibrahim MI Crouse Karen A KA

Acta crystallographica. Section E, Structure reports online 20120404 Pt 5

The title compound, [Zn(C(15)H(14)N(3)S(2))(2)], contains two chemically equivalent Schiff base anions that are coordinated to the Zn(II) ion as tridentate N,N',S-chelating ligands, creating a distorted octa-hedral environment [the smallest angle being 75.40 (6)° and the widest angle being 162.87 (6)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 85.65 (5)°. Weak C-H⋯S hydrogen bonds are also observed. ...[more]

PMID: 22590061

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{S-Benzyl 3-[(6-methyl-pyridin-2-yl)-methyl-idene]dithio-carbazato}nickel(II) monohydrate.

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