Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis[benzyl 3-(3-phenyl-prop-2-enyl-idene)dithio-carbazato-?(2)N(3),S]cadmium.

ABSTRACT: In the title complex, [Cd(C(17)H(15)N(2)S(2))(2)], the Cd(II) ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bis-phenoidal. The two deprotonated Schiff base ligands chelate the Cd(II) ion through the azomethine N and the thiol-ate S atom. The dihedral angle between the two chelating ligands is 84.01?(9)°. Weak inter-molecular C-H?S inter-actions lead to the formation of chains along the c axis.

SUBMITTER: Reza MS

PROVIDER: S-EPMC3393227 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis[benzyl 3-(3-phenyl-prop-2-enyl-idene)dithio-carbazato-κ(2)N(3),S]cadmium.

Reza M S MS Islam M A A A A MA Tarafder M T H MT Sheikh M C MC Zangrando E E

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

In the title complex, [Cd(C(17)H(15)N(2)S(2))(2)], the Cd(II) ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bis-phenoidal. The two deprotonated Schiff base ligands chelate the Cd(II) ion through the azomethine N and the thiol-ate S atom. The dihedral angle between the two chelating ligands is 84.01 (9)°. Weak inter-molecular C-H⋯S inter-actions lead to the formation of chains along t ...[more]

PMID: 22807795

Similar Datasets

Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)dithio-carbazato-κ(2)N',S]mercury(II).

Project description:In the title compound, [Hg(C(17)H(15)N(2)S(2))(2)], the Hg(II) ion lies on a crystallographic twofold rotation axis giving a very distorted tetra-hedral coordination geometry best described as bis-phenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitro-gen and the thiol-ate sulfur donors. The dihedral angle between the two chelating ligand moieties is 79.75 (10)°. In the crystal, weak C-H⋯S inter-actions give rise to chains extending along the c axis.

| S-EPMC3393190 | biostudies-literature

Benzyl 3-[(E,E)-3-phenyl-prop-2-enyl-idene]dithio-carbazate.

Project description:The title compound, C(17)H(16)N(2)S(2), a dithio-carbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenyl-idine group. The 3-phenyl-prop-2-enyl-idene and dithio-carbazate fragments lie essentially in the same plane, with a maximum deviation from that plane of 0.074?(2)?Å, while the dihedral angle between the 3-phenyl-prop-2-enyl-idene and the benzyl group is 77.78?(7)°. In the crystal structure, mol-ecules are linked by an N-H?S hydrogen bond and a weak C-H?S inter-action involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane. The crystal structure is also stabilized by C-H?? inter-actions.

| S-EPMC2961473 | biostudies-literature

Methyl 3-[(E,E)-3-phenyl-prop-2-enyl-idene]dithio-carbazate.

Project description:In the title compound, C(11)H(12)N(2)S(2), the dithio-carbazate group adopts an EE configuration with respect to the C=C and C=N bonds of the propenyl-idene group. The atoms of the propenyl-idene and dithio-carbazate unit are essentially co-planar, with a maximum deviation of 0.058 (1) Å; the phenyl ring forms a dihedral angle of 18.3 (1)° with this fragment. In the crystal, mol-ecules form inversion dimers via pairs of N-H⋯S hydrogen bonds involving the terminal S atom.

| S-EPMC3008995 | biostudies-literature

Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)hydrazinecarbodithio-ato-κN',S]copper(II).

Project description:The Cu(II) atom of the title complex, [Cu(C(17)H(15)N(2)S(2))(2)], lies on a twofold rotation axis, and is in a distorted tetra-hedral geometry with the two bidentate N(2)S(2) Schiff bases. In the crystal structure, the mol-ecules are inter-connected into chains along the c axis by weak C-H⋯S inter-molecular inter-actions. The crystal packing is further stabilized by C-H⋯π inter-actions.

| S-EPMC2960465 | biostudies-literature

Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)hydrazinecarbodithio-ato-κN',S]zinc(II).

Project description:In the title Zn(II) complex, [Zn(C(17)H(15)N(2)S(2))(2)], the Zn(II) atom lies on a twofold rotation axis. It exists in a tetra-hedral geometry, chelated by two deprotonated Schiff base ligands. The dihedral angle between each ligand is 71.48 (8)°. Mol-ecules are connected by weak C-H⋯S inter-molecular inter-actions into chains along the c axis. The crystal structure is further stabilized by C-H⋯π inter-actions involving the phenyl ring of the 3-phenyl-prop-2-enyl-idene unit.

| S-EPMC2961027 | biostudies-literature

Bis{S-benzyl 3-[(6-methyl-pyridin-2-yl)methyl-idene]dithio-carbazato}nickel(II).

Project description:The asymmetric unit of the title compound, [Ni(C(15)H(14)N(3)S(2))(2)], consists of two independent mol-ecules with similar configurations. Each Ni(2+) cation is coordinated in a cis-mode by two tridentate N,N',S-chelating Schiff base ligands, creating a distorted octa-hedron [the smallest angle being 77.57?(7)° and the widest being 168.97?(7)° for one mol-ecule, and 78.04?(7) and 167.55?(7)° for the second mol-ecule]. The dihedral angle between the mean coordination planes of the two ligands is 86.76?(7)° for one and 89.99?(7)° for the second mol-ecule. ?-? inter-actions between neighbouring pyridine rings with plane-to-plane distances of 3.540?(1) and 3.704?(1)?Å are observed.

| S-EPMC3344386 | biostudies-literature

Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) pyridine disolvate.

Project description:The Pd(II) ion in the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)°. The indole NH groups are bonded to the pyridine solvent mol-ecules via an N-H⋯N inter-action. The crystal structure is consolidated by inter-molecular C-H⋯S inter-actions.

| S-EPMC3051733 | biostudies-literature

Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-?N,S}palladium(II) N,N-dimethyl-formamide disolvate.

Project description:In the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The Pd(II) ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-planar geometry. In the crystal, the indolic NH groups are bonded to the dimethyl-formamide (DMF) solvent mol-ecules via an N-H?O inter-action. In addition, C-H?S inter-actions are observed.

| S-EPMC3050367 | biostudies-literature

4-Eth-oxy-N-(3-phenyl-prop-2-enyl-idene)aniline.

Project description:The title compound, C(17)H(17)NO, was prepared by the condensation of cinnamaldehyde with p-phenetidine in ethanol. The prop-2-enyl-idene group exhibits an E configuration at the N=C and C=C double bonds, with C-N-C-C and C-C-C-C torsion angles of -179.9 (3) and -175.9 (3)°, respectively. The prop-2-enyl-idene group is not strictly planar [maximum deviation = 0.054 (4) Å] and forms dihedral angles of 28.0 (3) and 34.9 (3)° with the attached aromatic rings.

| S-EPMC2961520 | biostudies-literature

N-[(E,Z)-1,3-Diphenyl-prop-2-enyl-idene]-N'-(1,3-dithio-lan-2-yl-idene)hydrazine.

Project description:Mol-ecules of the title compound, C(18)H(16)N(2)S(2), exist as the (2E, 1'Z)-isomer. The 1,3-dithiol-ane ring has an envelope conformation; the atoms of the C-C bond are disordered over two positions with occupancies of 0.47 (7) and 0.53 (7). The structure exhibits inter-molecular C-H⋯S and C-H⋯π(arene) hydrogen bonds.

| S-EPMC2961686 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data