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Chlorido[1-phenyl-3-(2,3,5,6-tetra-methyl-benz-yl)benzimidazol-2-yl-idene]silver(I).

ABSTRACT: In the title compound, [AgCl(C(24)H(24)N(2))], the terminal phenyl and tetra-methyl-benzene rings [which form a dihedral angle of 87.92?(14)°] make dihedral angles of 59.59?(11) and 83.19?(12)° with respect to the central benzimidazole ring system. The Ag-C and Ag-Cl single-bond lengths are 2.087?(3) and 2.3267?(9)?Å. The C-Ag-Cl bond angle is 172.84?(7)°. C-H?? inter-actions contribute to the stabilization of the crystal structure. A very weak ?-? stacking inter-action between adjacent tetra-methyl-benzene rings [centroid-centroid distance = 4.0610?(18)?Å] is also observed.

SUBMITTER: Akkurt M

PROVIDER: S-EPMC3344334 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Chlorido[1-phenyl-3-(2,3,5,6-tetra-methyl-benz-yl)benzimidazol-2-yl-idene]silver(I).

Akkurt Mehmet M Akkoç Senem S Gök Yetkin Y Dağdemir Yılmaz Y Tahir Muhammad Nawaz MN

Acta crystallographica. Section E, Structure reports online 20120413 Pt 5

In the title compound, [AgCl(C(24)H(24)N(2))], the terminal phenyl and tetra-methyl-benzene rings [which form a dihedral angle of 87.92 (14)°] make dihedral angles of 59.59 (11) and 83.19 (12)° with respect to the central benzimidazole ring system. The Ag-C and Ag-Cl single-bond lengths are 2.087 (3) and 2.3267 (9) Å. The C-Ag-Cl bond angle is 172.84 (7)°. C-H⋯π inter-actions contribute to the stabilization of the crystal structure. A very weak π-π stacking inter-action between adjacent tetra-me ...[more]

PMID: 22590100

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