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Bis[(1H-1,2,3-benzotriazol-1-yl)methyl 2,2-dimethyl-propano-ato-?N(3)]dichlorido-copper(II).

ABSTRACT: In the title compound, [CuCl(2)(C(12)H(15)N(3)O(2))(2)], the Cu(II) ion is located on an inversion center and is four-coordinated in a distorted square-planar geometry by two chloride anions and two N atoms from two (1H-1,2,3-benzotriazol-1-yl)methyl 2,2-dimethyl-propano-ate ligands. The Cl-Cu-N angles of 90.55?(9) and 89.45?(9)° are close to ideal values. In the crystal, weak ?-? stacking inter-actions are observed between inversion-related benzene rings [centroid-centroid distance = 4.0028?(6)?Å].

SUBMITTER: Cao G

PROVIDER: S-EPMC3344345 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Bis[(1H-1,2,3-benzotriazol-1-yl)methyl 2,2-dimethyl-propano-ato-κN(3)]dichlorido-copper(II).

Cao Gang G Guo Ting T Xu Sen S

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5

In the title compound, [CuCl(2)(C(12)H(15)N(3)O(2))(2)], the Cu(II) ion is located on an inversion center and is four-coordinated in a distorted square-planar geometry by two chloride anions and two N atoms from two (1H-1,2,3-benzotriazol-1-yl)methyl 2,2-dimethyl-propano-ate ligands. The Cl-Cu-N angles of 90.55 (9) and 89.45 (9)° are close to ideal values. In the crystal, weak π-π stacking inter-actions are observed between inversion-related benzene rings [centroid-centroid distance = 4.0028 (6) ...[more]

PMID: 22590111

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