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Dicyclo-hexyl-ammonium hydrogen phenyl-phospho-nate.

ABSTRACT: In the title salt, [(C(6)H(11))(2)NH(2)](+)·[C(6)H(5)PO(2)(OH)](-), the anion is monodeprotonated and acts as both a hydrogen-bond donor and acceptor. The anions are linked by pairs of O-H?O inter-actions, forming inversion dimers with R(2) (2)(8) ring motifs. These dimers are bridged by two dicyclo-hexyl-aminium cations via pairs of N-H?O hydrogen bonds, giving R(4) (4)(12) ring motifs, forming chains propagating along [010]. The chains are bridged by C-H?O inter-actions, forming a two-dimensional network lying parallel to (101).

SUBMITTER: Diop T 

PROVIDER: S-EPMC3344552 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Dicyclo-hexyl-ammonium hydrogen phenyl-phospho-nate.

Diop Tidiane T   Diop Libasse L   Maris Thierry T   Stoeckli-Evans Helen H  

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5

In the title salt, [(C(6)H(11))(2)NH(2)](+)·[C(6)H(5)PO(2)(OH)](-), the anion is monodeprotonated and acts as both a hydrogen-bond donor and acceptor. The anions are linked by pairs of O-H⋯O inter-actions, forming inversion dimers with R(2) (2)(8) ring motifs. These dimers are bridged by two dicyclo-hexyl-aminium cations via pairs of N-H⋯O hydrogen bonds, giving R(4) (4)(12) ring motifs, forming chains propagating along [010]. The chains are bridged by C-H⋯O inter-actions, forming a two-dimensio  ...[more]

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