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Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes.


ABSTRACT: The first examples of thiazol-5-ylidene complexes featuring group 9, 10 and 11 metal centers, have been prepared by deprotonation of a series of 2,3,4-triaryl-susbtituted thiazolium salts in the presence of the corresponding transition metal precursor.

SUBMITTER: Mendoza-Espinosa D 

PROVIDER: S-EPMC3371234 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes.

Mendoza-Espinosa Daniel D   Ung Gaël G   Donnadieu Bruno B   Bertrand Guy G  

Chemical communications (Cambridge, England) 20110830 38


The first examples of thiazol-5-ylidene complexes featuring group 9, 10 and 11 metal centers, have been prepared by deprotonation of a series of 2,3,4-triaryl-susbtituted thiazolium salts in the presence of the corresponding transition metal precursor. ...[more]

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