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Bis(acetato-?(2)O,O')(4,4'-dimethyl-2,2'-bipyridine-?(2)N,N')copper(II) monohydrate.

ABSTRACT: In the title compound, [Cu(C(2)H(3)O(2))(2)(C(12)H(12)N(2))(2)]·H(2)O, the Cu(II) atom exhibits a distorted octa-hedral coordination geometry, defined by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine ligand and four O atoms from two acetate ligands. In the crystal, O-H?O hydrogen bonds are observed between the coordinated carboxyl-ate O atoms and the solvent water mol-ecule.

SUBMITTER: Kaewthong A

PROVIDER: S-EPMC3379107 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Bis(acetato-κ(2)O,O')(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')copper(II) monohydrate.

Kaewthong Aphiwat A Sukwattanasinitt Mongkol M Muangsin Nongnuj N

Acta crystallographica. Section E, Structure reports online 20120516 Pt 6

In the title compound, [Cu(C(2)H(3)O(2))(2)(C(12)H(12)N(2))(2)]·H(2)O, the Cu(II) atom exhibits a distorted octa-hedral coordination geometry, defined by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine ligand and four O atoms from two acetate ligands. In the crystal, O-H⋯O hydrogen bonds are observed between the coordinated carboxyl-ate O atoms and the solvent water mol-ecule. ...[more]

PMID: 22719328

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