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Tetra-kis(ethyl pyridine-4-carboxyl-ate-?N)bis-(thio-cyanato-?N)cobalt(II).

ABSTRACT: In the title complex, [Co(NCS)(2)(C(8)H(9)NO(2))(4)], the Co(II) atom is six-coordinated by four N atoms from four ethyl pyridine-4-carboxyl-ate ligands in the equatorial plane and two N atoms of thio-cyanate ligands in the axial positions, showing a slightly distorted octa-hedral geometry. The structure exhibits disorder in one of the ethyl chains, which was refined using a two-site model with 0.70?(6):0.30?(6) occupancy.

SUBMITTER: Feng XL 

PROVIDER: S-EPMC3379116 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Tetra-kis(ethyl pyridine-4-carboxyl-ate-κN)bis-(thio-cyanato-κN)cobalt(II).

Feng Xiu-Ling XL   Zhang Yu-Ping YP  

Acta crystallographica. Section E, Structure reports online 20120519 Pt 6

In the title complex, [Co(NCS)(2)(C(8)H(9)NO(2))(4)], the Co(II) atom is six-coordinated by four N atoms from four ethyl pyridine-4-carboxyl-ate ligands in the equatorial plane and two N atoms of thio-cyanate ligands in the axial positions, showing a slightly distorted octa-hedral geometry. The structure exhibits disorder in one of the ethyl chains, which was refined using a two-site model with 0.70 (6):0.30 (6) occupancy. ...[more]

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