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Tetra-kis(1-ethyl-1H-imidazole-?N)bis-(thio-cyanato-?N)cadmium(II).

ABSTRACT: The structure of the title compound, [Cd(NCS)(2)(C(5)H(8)N(2))(4)], consists of isolated mol-ecules of [Cd(NCS)(2)(Eim)(4)] (Eim = 1-ethyl-imidazole), which contain a compressed octa-hedral CdN(6) chromophore. The NCS(-) anions are trans and four N atoms from the 1-ethyl-imidazole ligands define the equatorial plane. The mean Cd-N(Eim) and Cd-N(NCS) distances are 2.334?(4) and 2.379?(5)?Å, respectively. Weak C-H?N inter-actions contribute to the crystal packing stability.

SUBMITTER: Li RX 

PROVIDER: S-EPMC2983676 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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Tetra-kis(1-ethyl-1H-imidazole-κN)bis-(thio-cyanato-κN)cadmium(II).

Li Rong-Xun RX   Wu Qi-Ye QY   Liu Fa-Qian FQ  

Acta crystallographica. Section E, Structure reports online 20100213 Pt 3

The structure of the title compound, [Cd(NCS)(2)(C(5)H(8)N(2))(4)], consists of isolated mol-ecules of [Cd(NCS)(2)(Eim)(4)] (Eim = 1-ethyl-imidazole), which contain a compressed octa-hedral CdN(6) chromophore. The NCS(-) anions are trans and four N atoms from the 1-ethyl-imidazole ligands define the equatorial plane. The mean Cd-N(Eim) and Cd-N(NCS) distances are 2.334 (4) and 2.379 (5) Å, respectively. Weak C-H⋯N inter-actions contribute to the crystal packing stability. ...[more]

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