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Di-?-glutarato-?(4)O(1):O(5)-bis-{aqua-[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-?(2)N(2),N(3)]copper(II)}.

ABSTRACT: In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different glutarate dianions, while a water mol-ecule is located at the apical position. Of the two water H atoms, one is engaged in an intra-molecular O-H?O hydrogen bond, whereas the second is engaged in an inter-molecular O-H?O hydrogen bond. The intermolecular hydrogen bonds lead to the formation of a chain along [010].

SUBMITTER: Xu W

PROVIDER: S-EPMC3379125 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Di-μ-glutarato-κ(4)O(1):O(5)-bis-{aqua-[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)N(2),N(3)]copper(II)}.

Xu Wei W Feng Lan-Jing-Qian LJ

Acta crystallographica. Section E, Structure reports online 20120526 Pt 6

In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different glutarate dianions, while a water mol-ecule is located at the apical position. Of the two water H atoms, one is engaged in an intra-molecular O-H⋯O hydrogen bond, whereas the second is engaged in an in ...[more]

PMID: 22719346

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