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2-((E)-{[4-(Hy-droxy-meth-yl)phen-yl]imino}-meth-yl)phenol.

ABSTRACT: The title compound, C(14)H(13)NO(2), adopts the enol-imine tautomeric form, with an intra-molecular O-H?N hydrogen bond which generates an S(6) ring motif. The dihedral angle between the aromatic rings is 7.85?(7)°. The crystal structure is stabilized by O-H?O, O-H?N and C-H?O hydrogen bonds, forming a two-dimensional array that stacks along the a axis. In addition, a C-H?? inter-action contributes to the stabilization of the crystal packing.

SUBMITTER: Mohamed SK

PROVIDER: S-EPMC3379224 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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2-((E)-{[4-(Hy-droxy-meth-yl)phen-yl]imino}-meth-yl)phenol.

Mohamed Shaaban K SK Abdelhamid Antar A AA Akkurt Mehmet M Fanwick Phillip E PE Maharramov A M AM

Acta crystallographica. Section E, Structure reports online 20120505 Pt 6

The title compound, C(14)H(13)NO(2), adopts the enol-imine tautomeric form, with an intra-molecular O-H⋯N hydrogen bond which generates an S(6) ring motif. The dihedral angle between the aromatic rings is 7.85 (7)°. The crystal structure is stabilized by O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds, forming a two-dimensional array that stacks along the a axis. In addition, a C-H⋯π inter-action contributes to the stabilization of the crystal packing. ...[more]

PMID: 22719422

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