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2-[(2-Chloro-phen-yl)(hy-droxy)meth-yl]phenol.

ABSTRACT: In the title compound, C13H11ClO2, the dihedral angle between the mean planes of the 2-chloro-phenyl and phenol rings is 87.4?(9)°. The methyl hy-droxy group lies nearly perpendicular to the plane of its attached benzene ring [O-C-C-C torsion angle = 84.3?(3)°]. The two hy-droxy groups lie on the same side of the mol-ecule and are in a slightly twisted gauche conformation [O-C-C-O torsion angle = 77.1?(8)°] to each other. In the crystal, O-H?O hydrogen bonds between nearby methyl-hydroxy groups form dimers in alternating pairs aligned diagonally along the b axis. A view along the c axis reveals a hexa-meric aggregate mediated by a ring of six O-H?O hydrogen bonds generating an R 6 (6)(12) motif loop.

SUBMITTER: Prakasha G

PROVIDER: S-EPMC3793743 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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2-[(2-Chloro-phen-yl)(hy-droxy)meth-yl]phenol.

Prakasha G G Jasinski Jerry P JP Brown Jared S JS Yathirajan H S HS Ravishankara D K DK

Acta crystallographica. Section E, Structure reports online 20130713 Pt 8

In the title compound, C13H11ClO2, the dihedral angle between the mean planes of the 2-chloro-phenyl and phenol rings is 87.4 (9)°. The methyl hy-droxy group lies nearly perpendicular to the plane of its attached benzene ring [O-C-C-C torsion angle = 84.3 (3)°]. The two hy-droxy groups lie on the same side of the mol-ecule and are in a slightly twisted gauche conformation [O-C-C-O torsion angle = 77.1 (8)°] to each other. In the crystal, O-H⋯O hydrogen bonds between nearby methyl-hydroxy groups ...[more]

PMID: 24109330

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