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2-(Pyridin-2-yl)-1,3-oxathiane.

ABSTRACT: The title compound, C(9)H(11)NOS, exhibits a unique structural motif, with free rotation of the aliphatic oxathiane ring about the C-C bond connecting this moiety to the aromatic pyridine ring. The structure elucidation was undertaken due to its potential as a bidentate ligand for organometallic complexes. The oxathiane ring adopts the expected chair conformation, with the S atom in proximity to the N atom on the pyridine ring. The corresponding S-C-C-N torsion angle is 69.07?(14)°. In the crystal, mol-ecules aggregate as centrosymmetric pairs connected by pairs of C-H?N hydrogen bonds.

SUBMITTER: Turner D

PROVIDER: S-EPMC3379271 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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2-(Pyridin-2-yl)-1,3-oxathiane.

Turner David D Fratini Albert A Turro Claudia C Check Michael M Hunter Chad C

Acta crystallographica. Section E, Structure reports online 20120512 Pt 6

The title compound, C(9)H(11)NOS, exhibits a unique structural motif, with free rotation of the aliphatic oxathiane ring about the C-C bond connecting this moiety to the aromatic pyridine ring. The structure elucidation was undertaken due to its potential as a bidentate ligand for organometallic complexes. The oxathiane ring adopts the expected chair conformation, with the S atom in proximity to the N atom on the pyridine ring. The corresponding S-C-C-N torsion angle is 69.07 (14)°. In the cryst ...[more]

PMID: 22719469

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