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5,5-Dimethyl-2,2-bis-(pyridin-2-yl)-1,3-diazinane.

ABSTRACT: In the mol-ecule of the title compound, C(16)H(20)N(4), the 1,3-diazinane ring adopts a chair conformation and the dihedral angle formed by the pyridine rings is 78.64?(8)°. The mol-ecular conformation is stabilized by an intra-molecular C-H?N hydrogen bond, forming an S(6) ring motif. In the crystal, centrosymmetrically related mol-ecules are linked into dimers by pairs of N-H?N hydrogen bonds, generating rings of R(2) (2)(10) graph-set motif.

SUBMITTER: Warad I

PROVIDER: S-EPMC3379365 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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5,5-Dimethyl-2,2-bis-(pyridin-2-yl)-1,3-diazinane.

Warad Ismail I Alruwaili Afaf A Al-Resayes Saud I SI Choudhary M Iqbal MI Yousuf Sammer S

Acta crystallographica. Section E, Structure reports online 20120519 Pt 6

In the mol-ecule of the title compound, C(16)H(20)N(4), the 1,3-diazinane ring adopts a chair conformation and the dihedral angle formed by the pyridine rings is 78.64 (8)°. The mol-ecular conformation is stabilized by an intra-molecular C-H⋯N hydrogen bond, forming an S(6) ring motif. In the crystal, centrosymmetrically related mol-ecules are linked into dimers by pairs of N-H⋯N hydrogen bonds, generating rings of R(2) (2)(10) graph-set motif. ...[more]

PMID: 22719563

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