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9-(2-Bromo-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

ABSTRACT: In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (-), adjacent cations are linked through C-Br?? and ?-? contacts [centroid-centroid distance = 3.744?(2)?Å], and neighbouring cations and anions via C-H?O, C-F?? and S-O?? inter-actions. The acridine and benzene ring systems are oriented at a dihedral angle of 18.7?(1)°. The carb-oxy group is twisted at an angle of 69.3?(1)° relative to the acridine skeleton. The mean planes of adjacent acridine moieties are either parallel or inclined at an angle of 27.8?(1)° in the lattice.

SUBMITTER: Trzybinski D

PROVIDER: S-EPMC3379313 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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9-(2-Bromo-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

Trzybiński Damian D Sieradzan Andrzej A Krzymiński Karol K Błażejowski Jerzy J

Acta crystallographica. Section E, Structure reports online 20120516 Pt 6

In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (-), adjacent cations are linked through C-Br⋯π and π-π contacts [centroid-centroid distance = 3.744 (2) Å], and neighbouring cations and anions via C-H⋯O, C-F⋯π and S-O⋯π inter-actions. The acridine and benzene ring systems are oriented at a dihedral angle of 18.7 (1)°. The carb-oxy group is twisted at an angle of 69.3 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine moieties are either ...[more]

PMID: 22719511

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