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Methyl 2-{6-[(1-meth-oxy-1-oxopropan-2-yl)amino-carbon-yl]pyridine-2-carboxamido}-propano-ate.


ABSTRACT: In the title compound, C(15)H(19)N(3)O(6), the amide planes are inclined at dihedral angles of 0.8?(6) and 12.1?(3)° with respect to the central pyridine ring. The mean planes of the corresponding methyl acetate groups form dihedral angles of 41.76?(13) and 86.48?(15)°, respectively with the mean plane of pyridine ring. A pair of weak intra-molecular N-H?N hydrogen bonds generate an S(5)S(5) ring motif in the mol-ecule. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds into [001] chains. The chains are cross-linked by C-H?O hydrogen bonds into layers lying parallel to bc plane. The crystal packing also features a C-H?? inter-action.

SUBMITTER: Al-Omar MA 

PROVIDER: S-EPMC3379408 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Methyl 2-{6-[(1-meth-oxy-1-oxopropan-2-yl)amino-carbon-yl]pyridine-2-carboxamido}-propano-ate.

Al-Omar Mohamed A MA   Amr Abdel-Galil E AG   Ghabbour Hazem A HA   Chia Tze Shyang TS   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20120523 Pt 6


In the title compound, C(15)H(19)N(3)O(6), the amide planes are inclined at dihedral angles of 0.8 (6) and 12.1 (3)° with respect to the central pyridine ring. The mean planes of the corresponding methyl acetate groups form dihedral angles of 41.76 (13) and 86.48 (15)°, respectively with the mean plane of pyridine ring. A pair of weak intra-molecular N-H⋯N hydrogen bonds generate an S(5)S(5) ring motif in the mol-ecule. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds into [001] cha  ...[more]

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