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Catena-Poly[[[diaqua-(1,10-phenan-thro-line)manganese]-?-3-[3-(carboxyl-ato-meth-oxy)phen-yl]acrylato] monohydrate].

ABSTRACT: The title compound, [Mn(C??H?O?)(C??H?N?)(H?O)?]·H?O, was obtained under hydro-thermal conditions. The coordination environment of the Mn(II) atom is a distorted MnN?O? octa-hedron defined by two N atoms from 1,10-phenanthroline, two water O atoms and two carboxyl-ate O atoms from two acrylate anions. The bis-monodentate coordination mode of the anion leads to the formation of chains propagating in [010]. Inter-molecular O-H?O hydrogen bonds link the chains into a two-dimensional network parallel to (100). In the voids of this arrangement, disordered lattice water mol-ecules are present.

SUBMITTER: Ji J

PROVIDER: S-EPMC3393182 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[[diaqua-(1,10-phenan-thro-line)manganese]-μ-3-[3-(carboxyl-ato-meth-oxy)phen-yl]acrylato] monohydrate].

Ji Jun J Yang Yuan-Fa YF Wen Yi-Hang YH

Acta crystallographica. Section E, Structure reports online 20120616 Pt 7

The title compound, [Mn(C₁₁H₈O₅)(C₁₂H₈N₂)(H₂O)₂]·H₂O, was obtained under hydro-thermal conditions. The coordination environment of the Mn(II) atom is a distorted MnN₂O₄ octa-hedron defined by two N atoms from 1,10-phenanthroline, two water O atoms and two carboxyl-ate O atoms from two acrylate anions. The bis-monodentate coordination mode of the anion leads to the formation of chains propagating in [010]. Inter-molecular O-H⋯O hydrogen bonds link the chains into a two-dimensional network paralle ...[more]

PMID: 22807750

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Bis(?-5-carboxyl-ato-1-carboxyl-ato-methyl-2-oxidopyridinium)-?O:O;?O:O-[diaqua-(phenan-throline-?N,N')manganese(II)] dihydrate.

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