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[2-(1-{2-[Aza-nid-yl(ethyl-sulfan-yl)methyl-idene-?N]hydrazin-1-yl-idene-?N(1)}eth-yl)phenolato-?O](dimethyl sulfoxide-?O)dioxidomolybdenum(VI).

ABSTRACT: The Mo(VI) atom in the title complex, [Mo(C(11)H(13)N(3)OS)O(2)(C(2)H(6)OS)], is N,N',O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octa-hedral N(2)O(4) donor set. The most prominent feature of the crystal packing is the formation of inversion dimers via pairs of N-H?O hydrogen bonds and eight-membered {?HNMoO}(2) loops. The Schiff base ligand is disordered over two orientations of equal occupancy.

SUBMITTER: Takjoo R

PROVIDER: S-EPMC3393203 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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[2-(1-{2-[Aza-nid-yl(ethyl-sulfan-yl)methyl-idene-κN]hydrazin-1-yl-idene-κN(1)}eth-yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI).

Takjoo Reza R Ng Seik Weng SW Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20120620 Pt 7

The Mo(VI) atom in the title complex, [Mo(C(11)H(13)N(3)OS)O(2)(C(2)H(6)OS)], is N,N',O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octa-hedral N(2)O(4) donor set. The most prominent feature of the crystal packing is the formation of inversion dimers via pairs of N-H⋯O hydrogen bonds and eight-membered {⋯HNMoO}(2) loops. The Schiff base ligand is disordered over two orientations of equal occupancy. ...[more]

PMID: 22807771

Similar Datasets

[2-(1-{2-[Aza-nid-yl(ethyl-sulfan-yl)methyl-idene-?N]hydrazin-1-yl-idene-?N¹}eth-yl)phenolato-?O](pyridine-?N)nickel(II).

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| S-EPMC3238997 | biostudies-literature

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