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2-[(E)-(4-Fluoro-benzyl-imino)-meth-yl]-4-methyl-phenol.

ABSTRACT: In the title Schiff base compound, C(15)H(14)FNO, the benzene rings make a dihedral angle of 72.75 (13)°. The mol-ecular structure is stabilized by an intra-molecular O-H⋯N hydrogen bond. In the crystal, weak π-π stacking occurs between the phenol rings of inversion-related mol-ecules, the centroid-centroid distance being 3.7731 (14) Å.

SUBMITTER: Jin YB

PROVIDER: S-EPMC3393957 | biostudies-literature |

REPOSITORIES: biostudies-literature

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2-[(E)-Benzyl-imino-meth-yl]-4-methyl-phenol.

Project description:In the title Schiff base, C(15)H(15)NO, the benzene rings form a dihedral angle of 74.91 (1)°. There is a strong intra-molecular O-H⋯N hydrogen bond.

| S-EPMC2961287 | biostudies-literature

4-Fluoro-2-[(3-methyl-phen-yl)imino-meth-yl]phenol.

Project description:The title compound, C(14)H(12)FNO, crystallizes as the trans phenol-imine tautomer. The two benzene rings are essentially coplanar, being inclined to one another by 9.28?(7)°. This is at least in part due to the intra-molecular O-H?N hydrogen bond between the hy-droxy O atom and the imine N atom. The crystal structure is stabilized by an array of weak C-H?O and C-H?F inter-actions, which link the mol-ecules into a stable three-dimensional network.

| S-EPMC3344028 | biostudies-literature

(E)-2-(Benzyl-imino-meth-yl)-4,6-dibromo-phenol.

Project description:The title compound, C(14)H(11)Br(2)NO, was prepared by the condensation of benzyl-amine and 3,5-dibromo-2-hydroxy-benzaldehyde. The crystal structure is stabilized by aromatic π-π stacking inter-actions between the phenol rings of neighbouring mol-ecules [centroid-centroid distance = 3.530 (5) Å]. In addition, the stacked mol-ecules exhibit inter-molecular C-H⋯π and intra-molecular O-H⋯N inter-actions.

| S-EPMC2962031 | biostudies-literature

2-[(E)-(4-Fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenol.

Project description:In the title Schiff base, C(15)H(14)FNO(2), the dihedral angle between the benzene rings is 53.32?(8)°. In the crystal, mol-ecules related by a twofold rotation axis are linked by pairs of C-H?O hydrogen bonds into dimers with R(2) (2)(18) ring motifs. An intra-molecular O-H?N hydrogen bond is also observed.

| S-EPMC3414325 | biostudies-literature

2-Fluoro-6-[(E)-(pyridin-2-yl)imino-meth-yl]phenol.

Project description:The title compound, C(12)H(9)FN(2)O, is almost planar (r.m.s. deviation for the 16 non-H atoms = 0.019?Å), a conformation stabilized by an intra-molecular O-H?N hydrogen bond, which generates an S(6) ring. In the crystal, inversion dimers linked by pairs of C-H?O hydrogen bonds generate R(2) (2)(16) loops.

| S-EPMC3239042 | biostudies-literature

(E)-2-[(1-Benzyl-piperidin-4-yl)imino-meth-yl]phenol.

Project description:There are two mol-ecules in the asymmetric unit of the title compound, C(19)H(22)N(2)O. Both mol-ecules have an E conformation about their C=N bonds and both piperdine rings adopt chair conformations with their N atoms adopting pyramidal geometries [bond angle sums = 329.8?(4) and 330.2?(4)°]. Both mol-ecules feature an intra-molecular O-H?N hydrogen bond, which generates an S(6) ring. The dihedral angles between the phenyl and benzene ring planes are 45.97?(18) and 66.0?(2)°. Short O-H?O contacts occur in the crystal.

| S-EPMC3254437 | biostudies-literature

2-Methyl-6-[2-(trifluoro-meth-yl)phenyl-imino-meth-yl]phenol.

Project description:The title compound, C(15)H(12)F(3)NO, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The dihedral angle between the aromatic rings is 38.79?(5)°. The mol-ecular structure is stabilized by an intra-molecular O-H?N hydrogen bond, which generates an S(6) ring. In addition, there is an intra-molecular short C-H?F contact.

| S-EPMC2971260 | biostudies-literature

(E)-2-[(3-Fluoro-phen-yl)imino-meth-yl]-4-(trifluoro-meth-oxy)phenol.

Project description:The title compound, C(14)H(9)F(4)NO(2), is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The H atom is located on the hydr-oxy O atom rather than on the N atom. This H atom is involved in a strong intra-molecular O-H?N hydrogen bond. The mol-ecule is almost planar, the angle between the benzene rings being 2.14?(13)°.

| S-EPMC2983675 | biostudies-literature

4-[(E)-(4-Methyl-phen-yl)imino-meth-yl]phenol.

Project description:In the title compound, C(14)H(13)NO, the two rings show significant deviation from coplanarity, with a dihedral angle between the two planes of 49.40 (5)°. The hy-droxy group is involved in an inter-molecular O-H⋯N hydrogen bond, forming an extended one-dimensional zigzag chain along (001).

| S-EPMC3297943 | biostudies-literature

2-Benzyl-imino-meth-yl-6-bromo-4-chloro-phenol.

Project description:The title mol-ecule, C(14)H(11)BrClNO, adopts a trans configuration with respect to the C=N double bond. The dihedral angle between the two aromatic rings is 70.4 (5)°. An intra-molecular O-H⋯N hydrogen bond is observed between the hydroxyl and imine groups.

| S-EPMC2960476 | biostudies-literature

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