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Hierarchical organization of a robust porphyrin cage self-assembled by hydrogen bonds.

ABSTRACT: Porphyrins appended with four rigid hydrogen bonding motifs on the meso positions were synthesized and self-assembled into a cofacial cage with four complementary bis(decyl)melamine units in dry solvents. The hydrocarbon chains on the melamine mediate the formation of nanofilms on surfaces as the solvent slowly evaporates.

SUBMITTER: Singh S

PROVIDER: S-EPMC3396184 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Hierarchical organization of a robust porphyrin cage self-assembled by hydrogen bonds.

Singh Sunaina S Aggarwal Amit A Farley Christopher C Hageman Brian A BA Batteas James D JD Drain Charles Michael CM

Chemical communications (Cambridge, England) 20110525 25

Porphyrins appended with four rigid hydrogen bonding motifs on the meso positions were synthesized and self-assembled into a cofacial cage with four complementary bis(decyl)melamine units in dry solvents. The hydrocarbon chains on the melamine mediate the formation of nanofilms on surfaces as the solvent slowly evaporates. ...[more]

PMID: 21614367

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